Thomas Tuchel's side were booed off by England fans in the RCDE Stadium after failing to impress against a team ranked 173rd in the world.
The England captain, who won the first major title of his career with the Bundesliga trophy this season, did find the target in the 86th minute, slotting in from close range for his 26th league goal of the season.
Bayern Munich were crowned German champions for the 34th time on Sunday, giving striker Harry Kane his first major trophy, after second-placed Bayer Leverkusen drew 2-2 at Freiburg.
Harry Kane is no stranger to waiting. After all, you don’t spend your prime years at Tottenham without developing monk-like levels of patience. But this? This could test even his famously stoic resolve.
The victory took Bayern nine points clear of second-placed Bayer Leverkusen, who play at St Pauli on Sunday.
Ten years ago today, Harry Kane made his England debut. We've chartered his rise from debutant scorer, to the nation's favourite son.
Kane has also scored 76 goals in just 82 games for German giants Bayern Munich.
Harry Kane scored a goal and set up another as Bayern Munich won 2-0 at Bayer Leverkusen on Tuesday, going through to the Champions League quarter-finals 5-0 on aggregate.
Harry Kane struck twice as Bayern Munich eased to a 3-0 home win over 10-man Bayer Leverkusen on Wednesday, putting them on track for the Champions League quarter-finals.
The 31-year-old, top scorer in Germany's top flight this season, was taken off in the first half of the 1-1 draw at Borussia Dortmund on Saturday.
Harry Kane will be the dangerman against PSG as the English striker will be looking to add to the 20 goals he has scored in all competitions this season. His hattrick on the weekend against Augsburg saw him become the fastest to 50 Bundesliga goals
Bayern Munich striker Harry Kane hit back at criticism levelled at him, saying he would do his "talking on the pitch" after becoming the fastest to 50 goals in Bundesliga history on Friday.
At Euro 2024 last summer, Kane often looked laboured and was substituted in all four knockout games as England reached the final.
England captain Harry Kane expects incoming coach Thomas Tuchel to have the backing of fans despite his nationality, adding that the German's track record could help the team end a 58-year wait for a major trophy.
England play Greece away on Thursday followed by Ireland three days later at Wembley but nine players, some of them regular starters, who were called up by interim boss Lee Carsley have pulled out due to injuries.
Bayern Munich maintained their perfect start to the season and jumped to the top of the Bundesliga table after hammering newly-promoted Holstein Kiel 6-1. Jamal Musiala scored the third fastest goal in Bundesliga history, giving Bayern the lead after just 15 seconds.
Harry Kane has a hunger to prove his doubters wrong, as he celebrated his 100th England cap by scoring twice against Finland.
The 31-year-old Bayern Munich striker, who has scored 66 goals in 99 appearances for England since his debut in 2015, is the first player to become an England men's centurion since striker Wayne Rooney in November 2014.
England captain Harry Kane plans to follow Cristiano Ronaldo's example by extending his career as long as possible.
