The Brazil star opened the scoring after a superb defence-splitting pass by Jude Bellingham on 40 minutes and then set up Federico Valverde for the all-important second goal in first-half stoppage time.
New Real Madrid coach Xabi Alonso warned his team's stars including Vinicius Junior and Kylian Mbappe on Wednesday that they must all pitch in defensively.
Four Atletico Madrid ultras have been handed suspended jail sentences for hanging a dummy of Real Madrid star Vinicius Junior from a bridge in what police deemed a "hate crime", judicial sources said on Monday.
Carlo Ancelotti might not have gotten the start he had wanted as Brazil coach, but the Italian is definitely gaining the confidence of his players.
Ancelotti, who guided the Spanish giants to several titles alongside the Brazilian forward, including two Champions League triumphs and two LaLiga crowns, said that his unique ability to unsettle opposing defences made him a vital asset.
Vinicius Jr missed his second penalty in less than a month as LaLiga champions Real Madrid were shocked at home by Valencia 2-1 on Saturday, leaving the door open for rivals Barcelona to extend their lead on top of the LaLiga standings.
Madrid's two superstar forwards, as well as defender Antonio Rudiger and midfielder Dani Ceballos, face potential punishment ahead of their quarter-final first leg clash at Arsenal on April 8.
“We have to rethink everything we’ve been doing, because the demands will come; the people want us to win,” he said.
Kylian Mbappe and Vinicius Junior were both on target for Real Madrid as they beat Rayo Vallecano 2-1 on Sunday to pull level with La Liga leaders Barcelona.
Rodri, a first-time winner of the award, was instrumental in helping his team win an unprecedented fourth successive Premier League trophy last season. He was also named best player at this year's European Championship after Spain lifted a record-extending fourth title.
Vinicius was not among the nominees who paraded onto the stage at the Paris' Chatelet Theatre where the ceremony was held.
The men's shortlist for the 2023/24 edition of the prestigious individual award is the first since 2003 to feature neither Lionel Messi nor Cristiano Ronaldo who hoovered up the prize 13 times between them.
Vinicius Jr's remarkable performances at Real Madrid have put the 24-year-old forward as the odds-on favourite to claim his first Ballon d'Or when the award for the best player in the world is announced in Paris on Monday.
The viral social media campaign before the September 29 clash encouraged Atletico fans to arrive at the club's Metropolitano stadium and utter "degrading and discriminatory insults with racist connotations" against a Real player, police said.
Real Madrid duo Thibaut Courtois and Rodrygo are likely to miss the Clasico clash with La Liga leaders Barcelona on Saturday with injury problems.
"Vinicius is going to win (the Ballon d'Or), not for what he did tonight, but for what he did last year. These three goals are already going to count for next year's Ballon d'Or, that's for sure. He is a player who gets whistled at because he can make a difference."
Vinicius suffered a neck injury during Real Madrid's 2-0 home win against Villarreal on Saturday, the club said.
Real Madrid coach Carlo Ancelotti said Monday his team's "many styles" of play have helped them go 38 La Liga matches without defeat.
Vinicius Junior's decisive impact helped Real Madrid come from behind to beat a determined Espanyol side 4-1 on Saturday and move a point behind La Liga leaders Barcelona.